Layered Hybrid iron Fluorides

نویسندگان

چکیده

The first examples of layered hybrid iron fluorides are reported. In the reactions carried out, chain compound (H2pipz)FeF5·H2O always occurs as major phase, with compounds, (H2pipz)3Fe4F18·2H2O and (H2pipz)2Fe3F13·H2O, being isolated from some impurities. latter two compounds feature two-dimensional sheets corner-and edge-shared FeIIIF6 octahedra, resulting in distinct layer architectures. (H2pipz)FeF5·H2O, crystallises a one-dimensional structure exhibiting zig-zag [FeF5]∞ chains. This work opens up potential for much wider family transition-metal fluorides.

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ژورنال

عنوان ژورنال: Crystals

سال: 2022

ISSN: ['2073-4352']

DOI: https://doi.org/10.3390/cryst12101443